VITAX SAFETY DATA SHEET

ROSEGARDE

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

1.1 Product identifier
Trade name ROSEGARDE
Product code
1.2 Relevant identified uses of the substance or mixture and uses advised against Use Insecticide, Fungicide
1.3 Details of the supplier of the safety data sheet

Supplier
Telephone
Web
1.4 Emergency telephone no. Emergency telephone no.

Vitax Ltd, Owen St, Coalville, Leics LE67 3DE +44(0)1530 510060
www.vitax.co.uk

+44(0)1530 510060 (Office hours)

Date: 15 Sept 2015

SECTION 2: HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture

Classification in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended.

Acute aquatic toxicity: Category 1
H400 Very toxic to aquatic life.

Chronic aquatic toxicity: Category 1
H410 Very toxic to aquatic life with long lasting effects.

Classification according to EU Directives 67/548/EEC or 1999/45/EC

N Dangerous for the environment, R50/53

2.2 Label elements

Labelling in accordance with Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures, as amended.

Hazard label for supply/use required.

Hazardous components which must be listed on the label:

Myclobutanil
Cypermethrin cis/trans +/- 40/60

Pictogram
Signal word: Warning Hazard statements

H410 Very toxic to aquatic life with long lasting effects.
EUH401 To avoid risks to human health and the environment, comply with the instructions for

use.

Precautionary statements

101. P101  If medical advice is needed, have product container or label at hand.
102. P102  Keep out of reach of children.

P260 Do not breathe spray.
P271 Use only outdoors or in a well-ventilated area.

P501 Dispose of contents/container to a household waste recycling centre as hazardous waste except for empty containers which can be disposed of by recycling. Contact your local council for details.

2.3 Other hazards

Cutaneous sensations may occur, such as burning or stinging on the face and mucosae. However, these sensations cause no lesions and are of a transitory nature (max. 24 hours).

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2 Mixtures
Chemical nature
Any other liquids (AL)

Myclobutanil/Cypermethrin 0,075:0,05 g/l

Hazardous components

R-phrase(s) according to EC directive 67/548/EEC
Hazard statements according to Regulation (EC) No. 1907/2006

Classification

Name CAS-No. /
EC-No. EC Directive

67/548/EEC

Further information

For the full text of the R-phrases/ Hazard statements mentioned in this Section, see Section 16.

SECTION 4: FIRST AID MEASURES 4.1 Description of first aid measures

Regulation (EC) No 1272/2008

Conc. [%]

General advice Inhalation

Skin contact

Eye contact

Ingestion

Remove contaminated clothing immediately and dispose of safely.

Move the victim to fresh air and keep at rest. Call a physician or poison control center immediately.

Immediately wash with plenty of soap and water for at least 15 minutes. Warm water may increase the subjective severity of the irritation/paresthesia. This is not a sign of systemic poisoning. In case of skin irritation, application of oils or lotions containing vitamin E may be considered. If symptoms persist, call a physician.

Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Warm water may increase the subjective severity of the irritation/paresthesia. This is not a sign of systemic poisoning. Apply soothing eye drops, if needed anaesthetic eye drops. Get medical attention if irritation develops and persists.

Keep at rest. Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

4.2 Most important symptoms and effects, both acute and delayed

Symptoms

Local:, Skin and eye paraesthesia which may be severe, Usually transient with resolution within 24 hours, Skin, eye and mucous membrane irritation, Cough, Sneezing

Systemic:, Discomfort in the chest, Tachycardia, Hypotension, Nausea, Abdominal pain, Diarrhoea, Vomiting, Dizziness, Blurred vision, Headache, Anorexia, Somnolence, Coma, Convulsions, Tremors, Prostration, Airway hyperreaction, Pulmonary oedema, Palpitation, Muscular fasciculation, Apathy

4.3 Indication of any immediate medical attention and special treatment needed

Risks Treatment

This product contains a pyrethroid. Pyrethroid poisoning should not be confused with carbamate or organophosphate poisoning.

Local treatment: Initial treatment: symptomatic.

Systemic treatment: Initial treatment: symptomatic. Monitor: respiratory and cardiac functions. In case of ingestion gastric lavage should be considered in cases of significant ingestions only within the first 2 hours. However, the application of activated charcoal and sodium sulphate is always advisable. Keep respiratory tract clear. Oxygen or artificial respiration if needed. In case of convulsions, a benzodiazepine (e.g. diazepam) should be given according to standard regimens. If not effective, phenobarbital may be used. Contraindication: atropine. Contraindication: derivatives of adrenaline. There is no specific antidote. Recovery is spontaneous and without sequelae.

SECTION 5: FIREFIGHTING MEASURES 5.1 Extinguishing media

Suitable

Unsuitable

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

High volume water jet
Dangerous gases are evolved in the event of a fire.

In the event of fire and/or explosion do not breathe fumes. In the event of fire, wear self-contained breathing apparatus.

Remove product from areas of fire, or otherwise cool containers with water in order to avoid pressure being built up due to heat. Whenever possible, contain fire-fighting water by diking area with sand or earth.

5.2 Special hazards arising from the substance or mixture

5.3 Advice for firefighters

Special protective equipment for fire-fighters

Further information

SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1 Personal precautions, protective equipment and emergency procedures

Precautions

6.2 Environmental precautions

Avoid contact with spilled product or contaminated surfaces. When dealing with a spillage do not eat, drink or smoke.

Do not allow to get into surface water, drains and ground water. If spillage enters drains leading to sewage works inform local water company immediately. If spillage enters rivers or watercourses, inform the Environment Agency (emergency telephone number 0800 807060).

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for

disposal. Clean floors and contaminated objects with plenty of water. Additional advice Check also for any local site procedures.

6.4 Reference to other sections

Information regarding safe handling, see section 7.
Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13.

SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling No specific precautions required when handling unopened packs/containers; follow relevant manual handling advice. Ensure

adequate ventilation.
Advice on protection against No special precautions required.

fire and explosion

Hygiene measures When using, do not eat, drink or smoke. Wash hands immediately after work, if necessary take a shower.

7.2 Conditions for safe storage, including any incompatibilities

Requirements for storage areas and containers

Advice on common storage 7.3 Specific end uses

Store in original container and out of the reach of children, preferably in a locked storage area. Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from direct sunlight. Protect from freezing.

Keep away from food, drink and animal feedingstuffs. Refer to the label and/or leaflet.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Control parameters

Components

52315-07-8
*OES BCS: Internal Bayer CropScience “Occupational Exposure Standard”

CAS-No.

Control parameters

Update

Basis

OES BCS*

Cypermethrin cis/trans +/- 40/60

0.08 mg/m3 (OES BCS)

8.2 Exposure controls

Refer to COSHH assessment (Control of Substances Hazardous to Health (Amendment) Regulations 2004). Engineering controls should be used in preference to personal protective equipment wherever practicable. Refer also to COSHH Essentials.

Personal protective equipment

In normal use conditions personal protective equipment is not deemed to be necessary. If there is a potential for excessive exposure the following applies:

Respiratory protection

Respiratory protection is not required under anticipated circumstances of exposure.
Respiratory protection should only be used to control residual risk of short duration activities, when all reasonably practicable steps have been taken to reduce exposure at source e.g. containment and/or local extract ventilation. Always follow respirator manufacturer’s instructions regarding wearing and maintenance.

Hand protection

Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness of 0,4 mm). Wash when contaminated and dispose of when contaminated inside, when perforated or when contamination
on the outside cannot be removed. Wash hands frequently and always before eating, drinking, smoking or using the toilet.

Eye protection
Skin and body protection

Wear goggles (conforming to EN166, Field of Use = 5 or equivalent).

Wear standard coveralls and Category 3 Type 6 suit.
If there is a risk of significant exposure, consider a higher protective type suit.
Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties

Form

Colour

Density

Partition coefficient: n- octanol/water

clear liquid colourless
0.99 – 1.0 g/cm3

Myclobutanil: log Pow: 2.94

10.4 Conditions to avoid 10.5 Incompatible materials

10.6 Hazardous decomposition products

Extremes of temperature and direct sunlight. Store only in the original container.

No decomposition products expected under normal conditions of use.

SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects

Acute oral toxicity Acute inhalation toxicity

Acute dermal toxicity

Skin irritation

Eye irritation

Sensitisation

LD50 (rat) > 5,000 mg/kg

ATE > 5.0 mg/l
ATE – acute toxicity estimate

LD50 (rat) > 2,000 mg/kg No skin irritation (rabbit)
No eye irritation (rabbit) Non-sensitizing. (guinea pig)

Assessment repeated dose toxicity

Myclobutanil did not cause specific target organ toxicity in experimental animal studies. Cypermethrin caused neurobehavioral effects and/or neuropathological changes in animal studies.

Assessment Mutagenicity

Myclobutanil was not mutagenic or genotoxic in a battery of in vitro and in vivo tests. Cypermethrin was not mutagenic or genotoxic in a battery of in vitro and in vivo tests.

Assessment Carcinogenicity

Myclobutanil was not carcinogenic in lifetime feeding studies in rats and mice. Cypermethrin was not carcinogenic in lifetime feeding studies in rats and mice.

Assessment toxicity to reproduction

Myclobutanil caused reproduction toxicity in generation studies in rats only at dose levels also toxic to the parent animals.
Cypermethrin caused reproduction toxicity in a two-generation study in rats only at dose levels also toxic to the parent animals. The reproduction toxicity seen with Cypermethrin is related to parental toxicity.

Assessment developmental toxicity

Myclobutanil caused a reduced pup survival.
Cypermethrin did not cause developmental toxicity in rats and rabbits.

Further information

Cutaneous sensations may occur, such as burning or stinging on the face and mucosae.

9.2 Other information Further safety related physical-chemical data are not known. SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity
Thermal decomposition

10.2 Chemical stability

Stable under normal conditions.
Stable under recommended storage conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions when stored and handled according to prescribed instructions.

SECTION 12: ECOLOGICAL INFORMATION 12.1 Toxicity

Toxicity to fish

Toxicity to aquatic invertebrates

LC50 (Fish) > 0.27 mg/l Exposure time: 96 h

EC50 (Daphnia) > 0.017 mg/l Exposure time: 48 h

EC50 (Selenastrum capricornutum) > 21 mg/l Exposure time: 72 h

Toxicity to aquatic plants
12.2 Persistence and degradability

Biodegradability Myclobutanil:
not rapidly biodegradable

Cypermethrin:
not rapidly biodegradable

Koc Myclobutanil: Koc: 517 Cypermethrin: Koc: 26492 – 144652

12.3 Bioaccumulative potential

Bioaccumulation

12.4 Mobility in soil Mobility in soil

Myclobutanil: Bioconcentration factor (BCF) 8.3 Does not bioaccumulate.
Cypermethrin: Bioconcentration factor (BCF) 1,204 Does not bioaccumulate.

Myclobutanil: Slightly mobile in soils Cypermethrin: Immobile in soil

12.5 Results of PBT and vPvB assessment

PBT and vPvB assessment

12.6 Other adverse effects

Additional ecological information

Myclobutanil: This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).
Cypermethrin: This substance is not considered to be persistent, bioaccumulative and toxic (PBT). This substance is not considered to be very persistent and very bioaccumulative (vPvB).

No other effects to be mentioned.

SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods

Product

Contaminated packaging

Waste key for the unused product

Do not empty into drains.
Dispose of unused product in its container at a household waste site (civic amenity site).
Contact your local council (local authority) for details.

Dispose of empty container in the dustbin. Follow advice on product label and/or leaflet.

020108 agrochemical waste containing dangerous substances

SECTION 14: TRANSPORT INFORMATION

ADR/RID/ADN

14.1 UN number
14.2 Proper shipping name

14.3 Transport hazard class(es) Packing group
14.5 Environm. Hazardous Mark Hazard no.

Tunnel Code

3082

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CYPERMETHRINE SOLUTION)
9 14.4

III YES 90 E

This classification is in principle not valid for carriage by tank vessel on inland waterways. Please refer to the manufacturer for further information.

IMDG

14.1 UN number
14.2 Proper shipping name

14.3 Transport hazard class(es) Packing group
14.5 Marine pollutant

IATA

14.1 UN number
14.2 Proper shipping name

14.3 Transport hazard class(es) Packing group
14.5 Environm. Hazardous Mark

UK ‘Carriage’ Regulations

14.1 UN number
14.2 Proper shipping name

14.3 Transport hazard class(es) Packing group
14.5 Environm. Hazardous Mark Emergency action code

14.6 Special precautions for user

3082

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CYPERMETHRINE SOLUTION)
9 14.4

III YES

3082

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CYPERMETHRINE SOLUTION )
9 14.4

III YES

3082

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(CYPERMETHRINE SOLUTION)
9 14.4

III YES 3Z

See sections 6 to 8 of this Safety Data Sheet.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

No transport in bulk according to the IBC Code.

SECTION 15: REGULATORY INFORMATION
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture UK and Northern Ireland Regulatory References

This material may be subject to some or all of the following regulations (and any subsequent amendments). Users must ensure that any uses and restrictions as indicated on the label and/or leaflet are followed.

Transport

Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 (SI 2009 No 1348)
Merchant Shipping (Dangerous Goods and Marine Pollutants) Regulations 1997 (SI 1997 No 2367) Air Navigation Dangerous Goods Regulations 2002 (SI 2002 No 2786)

Supply and Use

Chemical (Hazard Information and Packaging for Supply) Regulations 2009 (SI 2009 No 716) Chemical (Hazard Information and Packaging for Supply) (Northern Ireland) Regulations 2009 Control of Substances Hazardous to Health Regulations 2002 (SI 2002 No 2677)
EH40 Occupational Exposure Limits – Table 1 List of approved workplace exposure limits Control of Pesticide Regulations 1986

Dangerous Substances and Explosive Atmospheres Regulations 2002

Waste Treatment

Environmental Protection Act 1990, Part II
Environmental Protection (Duty of Care) Regulations 1991
The Waste Management Licensing Regulations 1994 (as amended)
Hazardous Waste Regulations 2005 (Replacing Special Waste Regulations 1996 as amended) Landfill Directive
Regulation on Substances That Deplete the Ozone Layer 1994 (EEC/3093/94)
Water Resources Act 1991
Anti-Pollution Works Regulations 1999

Further information

WHO-classification: III (Slightly hazardous)

15.2 Chemical Safety Assessment

A chemical safety assessment is not required.

SECTION 16: OTHER INFORMATION Text of R-phrases mentioned in Section 3

R20/22 Harmful by inhalation and if swallowed. R22 Harmful if swallowed.

36. R36  Irritating to eyes.
37. R37  Irritating to respiratory system.

R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

R63 Possible risk of harm to the unborn child.

Text of the hazard statements mentioned in Section 3

H302 Harmful if swallowed.
H319 Causes serious eye irritation.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H361d Suspected of damaging the unborn child. H400 Very toxic to aquatic life.

410. H410  Very toxic to aquatic life with long lasting effects.
411. H411  Toxic to aquatic life with long lasting effects.

The above information is intended to give general health and safety guidance on the storage and transport of the product.
It is not intended to apply to the use of the product for which purposes the product label and any appropriate technical usage literature available should be consulted and any relevant licenses, consents or approvals complied with.

The requirements or recommendations of any relevant site or working procedure, system or policy in force or arising from any risk assessment involving the substance or product should take precedence over any of the guidance contained in this safety data sheet where there is a difference in the information given.

The information provided in this safety data sheet is accurate at the date of publication and will be updated as and when appropriate.
No liability will be accepted for any injury, loss or damage resulting from any failure to take account of information or advice contained in this safety data sheet.

Reason for Revision: Safety Data Sheet according to Regulation (EU) No. 453/2010.